Chapter 6 - Equilibria
Comprehensive Questions & Answers for Class 9 Chemistry (Punjab Board)
Dynamic Equilibrium vs Static Equilibrium
Dynamic Equilibrium:
Dynamic equilibrium occurs when the rates of the forward and reverse reaction are equal, with the concentrations of reactants and products remaining constant overtime. Both reactions continue to occur at the same rate.
Static Equilibrium:
Static equilibrium refers to a situation where there is no movement or reaction and everything is at rest.
Effects of Temperature in Reversible Reaction
The reaction is endothermic in the forward direction. Increasing the temperature will shift the equilibrium towards the production of more hydrogen and oxygen gas (right side), according to Le Chatelier principle.
Reversible Reaction Conditions
To get the maximum yield, you can manipulate the reaction conditions by:
- Removing the products as soon as they are formed.
- Increasing the concentration of reactants.
- Using a catalyst to speed up the reaction
- Without affecting the equilibrium.
- Lowering the temperature for exothermic reactions and adjusting pressure for reactions involving gases.
Conditions to Decrease the Time to Reach Equilibrium
To decrease the time to reach equilibrium you can:
- Increase the temperature (for reactions where higher temperature favor the forward reaction).
- Increase the concentration of reactants.
- Use a catalyst to speed up both the forward and reverse reactions
Effect of Increasing Pressure on Reaction at Equilibrium
Increasing pressure will shift the equilibrium towards the side with fewer gas molecules. In this case, since the number of moles of reactants (2 moles) equal the number of moles of products (2 moles), increasing pressure will have no significant effect on the equilibrium position.
Some Reactions are Irreversible & others are Reversible (Reason)
Some reactions are irreversible because the products formed are stable and cannot easily revert to the original reactants under normal conditions.Reversible reactions occur when the products can react to form the
reactants, often due to conditions such as temperature or pressure changes, or nature of the chemical bonds.
Combustion Reactions are Irreversible (Reason)
Combustion reactions are generally irreversible because the products (such as CO₂ and H₂O) are stable and are released as gases. The energy required to convert the product back into reactants is very high, making the reverse action highly unfavorable under normal conditions.
Irreversible vs Reversible Reactions
In some cases, an irreversible reaction can be made reversible by changing its reaction conditions (e.g.: temperature, pressure or adding catalyst) to allow its products to re-react and form reactants. Similarly, a reversible
reaction can become irreversible if conditions are altered to prevent the reverse reaction from occurring, such as removing a product or increasing energy barriers.
Identifying Reversible vs Irreversible Reaction
A reversible reaction can proceed in both directions under certain conditions, with reactants and products reaching dynamic equilibrium. An irreversible reaction, on the other hand proceed in one direction only and does
not reach equilibrium. Observing whether the reaction can be or if products are stable and do not change back to reactants indicates if it is reversible or irreversible.
Reversibility of Water Phase Changes
The phase changes in water (solid to liquid, liquid to vapor) are reversible. For example: ice can melt into water and water can evaporate into steam, and these changes can be reversed by lowering the temperature or increasing pressure. This makes them physical changes that can be undone.
Driving Equilibrium in Forward & Backward Direction - Le Chatelier's Principle
You can drive a reversible reaction at equilibrium in the following ways:
a) In the forward direction:
By increasing the concentration of reactants, increasing temperature for endothermic reactions, or removing products as they are formed, you can shift the equilibrium towards the formation of more products.
b) In the backward direction:
By decreasing the concentration of reactants, increasing temperature for exothermic reactions, or removing reactants, you can shift the equilibrium towards the reactants.According to Le Chatelier's principle, the system will
shift the equilibrium position to counteract the change and restore balance.
Change in Forward & Backward Reaction Rates to Reach Equilibrium
As a system approaches equilibrium the rate of the forward reaction decreases while the rate of the backward reaction increases, until they become equal, signifying that the system has reached dynamic equilibrium where
the concentrations of reactants and products remain constant. Essentially the forward and backward reactions are occurring at same rate.
Initially:
When a reaction starts, the forward reaction rate is high because there is a high concentration of reactants, while the backward reaction rate is low as there are minimal products present.
As the reaction proceeds:
As reactants are consumed and products are formed, the forward reaction rate gradually slows down due to the decreasing reactant concentration, while the backward reaction rate increases as more products are available to react.
At equilibrium:
The rates of the forward and backward reactions become equal, indicating that the system has reached a stable state, where the concentrations of reactants and products no longer change.
Effect of Catalyst on Reversible Reaction
Effect of catalyst on the reversible reaction:
A catalyst increases the rates of both the forward and reverse reactions in a reversible reaction. It lowers the activation energy required for both reactions to occur, which speeds up the process.
A catalyst in a reversible reaction speeds up both the forward and reverse reaction equally, allowing the system to reach equilibrium faster, but does not change the final equilibrium position or the equilibrium constant itself.
Essentially it just enables the reaction to reach equilibrium more quickly for both directions of the reactions.In a reversible reaction a catalyst enhances the rate of forward and backward reaction to the same extent. It
eventually helps the system to reach equilibrium faster.
Key Points About Catalyst and Reversible Reactions:
- Increase reaction rate.
- Low activation energy.
- No change in equilibrium position.
Ways to Force a Reversible Reaction to Completion
A reversible reaction can be forced to go to completion by manipulating the reaction conditions to favour the formation of the products. Here are some ways to do so:
1. Le Chatelier's Principle:
This principle states that when a system at equilibrium is subjected to a change in concentration, temperature or pressure, the equilibrium will shift in a direction that tends to counteract the effect of the change.
2. Concentration:
Increasing the concentration of reactants or decreasing the concentration of products can drive the reaction forward.
3.Temperature:
Changing the temperature can alter the equilibrium constant (Kc or Kp). If the reaction is exothermic, decreasing the temperature can favor the formation of products
4.Pressure:
For reactions involving gases, increasing the pressure can favor the formation of products.
5.Role of Catalyst:
Adding a catalyst can speed up the reaction, allowing it to reach completion faster.
6. Removal of Products:
Continuously removing the products from the reaction mixture can drive the reaction forward.
7. Equilibrium Constant:
If the equilibrium constant (Kc or Kp) is large, the reaction will naturally favour the formation of products. By applying one or more of these methods, you can force a reversible reaction to go to completion.
Effect of Temperature Change on Equilibrium - Le Chatelier's Principle
When the temperature of a reaction at equilibrium changes, the equilibrium position will shift to favor the endothermic reaction if the temperature increases, and the exothermic reaction if the temperature decreases;
essentially, the system will try to counteract the temperature change by absorbing heat (endothermic) or releasing heat (exothermic) according to Le Chatelier's Principle.
Key Points About Temperature and Equilibrium:
1. Endothermic Reactions:
If a reaction is endothermic (absorbs heat) increasing the temperature will shift the equilibrium towards the products.
2. Exothermic Reactions:
If a reaction is exothermic (releases heat) increasing the temperature will shift the equilibrium towards the reactants.
3. Equilibrium Constant (K):
The value of the equilibrium constant (K) changes with temperature, increasing for endothermic reactions and decreasing for exothermic reactions when temperature is raised.
Effect of Heat on Hydrated Copper Sulphate - Loss of Water of Crystallization
Hydrated copper sulphate (CuSO₄.5H₂O) is blue in color due to the water molecules that are bound within the crystal structure. The blue color is a result of the copper ions (Cu²⁺) interacting with the water molecules.
When hydrated copper sulphate is heated the water of crystallization is lost, and the salt turns white, forming anhydrous copper sulphate (CuSO₄). This change happens because the water molecules are no longer part of the
structure, and as a result, the characteristic blue color disappears.
Conclusion:
- Hydrated copper sulphate is blue due to the presence of water molecules.
- Upon heating, the water evaporates and the salt becomes white (anhydrous copper sulphate) which has no water molecules.
Industrial Conditions for Synthesis of Ammonia Gas - Haber Process
The synthesis of ammonia is typically carried out using the Haber process. To get the maximum yield of ammonia, the following conditions are used.
1. High Pressure:
Ammonia synthesis involves a reaction that produces fewer moles of gas (3 moles of gas on the left side and 2 moles on the right side). According to Le Chatelier's principle, increasing the pressure shifts the equilibrium
towards the side with fewer gas molecules, favouring the formation of ammonia.
2. Moderate Temperature:
The reaction is exothermic in the forward direction meaning it releases heat. While lower temperatures would favour the production of ammonia, very low temperature slow down the reaction rate. Therefore, a moderate
temperature (around 400-450°C) is chosen to balance the rate of reaction and the yield of ammonia.
3. Iron Catalyst:
An Iron catalyst is used to speed up the reaction without affecting the equilibrium. It allows the reaction to proceed at a fairly rate at the chosen moderate temperature.
Conclusion:
- High pressure to favour ammonia formation.
- Moderate temperature to maintain a good reaction rate and yield.
- Iron catalyst to speed up the reactio