Chapter 7 - Acid Base Chemistry
Comprehensive Questions & Answers for Class 9 Chemistry (Punjab Board)
Identification of Arrhenius Acids
The Arrhenius acids among the given compounds are HF (Hydrofluoric acid), H₂SO₃ (Sulphurous acid), and H₂S (Hydrosulphuric acid). These compounds dissociate in water to release hydrogen ions (H⁺), which is the characteristic behaviour of Arrhenius acids.
- HF: dissociates to form H⁺ and F⁻
- H₂SO₃: dissociates to form H⁺ and HSO₃⁻
- H₂S: dissociates to form H⁺ and HS⁻
Reaction of Calcium Metal with Dilute Sulphuric Acid
Calcium reacts with H₂SO₄ to produce hydrogen gas (H₂) and calcium sulphate (CaSO₄).
Reaction:
Ca(s)+H₂SO₄(aq) → CaSO₄(aq)+H₂(g)
Reaction of Acid with Carbonate - Salt Formation
The salt formed when hydrochloric acid (HCl) reacts with barium carbonate (BaCO₃) is Barium chloride (BaCl₂).
Reaction:
BaCO₃(s)+2HCl(aq) → BaCl₂(aq)+H₂O(l)+CO₂(g)
HSO₄⁻ as a Brønsted-Lowry Acid - Proton Donor Concept
HSO₄⁻ (Bisulphate ion) can donate a proton (H⁺) to form (SO₄²⁻) (sulphate ion). According to Brønsted-Lowry definition, an acid is a proton donor. Therefore, HSO₄⁻ is a Brønsted-Lowry acid.
Reaction:
HSO₄⁻ → SO₄²⁻+ H⁺
Why Stomach HCl is Not Edible - Role of Mucus Layer
While hydrochloric acid (HCl) is present in the stomach for digestion, it is highly concentrated and corrosive. The stomach lining is protected by a layer of mucus that prevents damage. However, if this protective layer is compromised, HCl can cause harm to the stomach, which is why concentrated HCl is not edible.
Chemical Name of Soap - Salt of Fatty Acid
Soap is a sodium or potassium salt of a fatty acid, typically called sodium stearate (C₁₇H₃₅COONa) when made from stearic acid.
Amphoteric Nature of Water
Water is amphoteric, meaning it can act as both an acid and a base depending on the substance it reacts with.
Basic Nature of Sodium Carbonate in Water
Na₂CO₃ behave like a base in water because it dissociates to form carbonate ions (CO₃²⁻), which accept protons (H⁺) and release hydroxide ions (OH⁻).
Nature of Sodium Bicarbonate - Weak Base
NaHCO₃ (sodium bicarbonate) is a weak base because it reacts with acids to release carbon dioxide (CO₂) and forms a weak basic solution.
Strong Acid vs Concentrated Acid
A strong acid completely dissociates in water, while a concentrated acid refers to the amount of acid present in a solution, regardless of its dissociation.
Arrhenius Concept of Acids and Bases
Arrhenius Concept of Acid and Base:
1. Arrhenius Acid:
a) Definition:
An acid is that substance which dissociates in water to give proton (H⁺) or hydroxonium ion (H₃O⁺).
b) Example:
H₂O
HCl(aq) ⇌ H₃O⁺(aq)++Cl⁻(aq)
2. Arrhenius Base:
a) Definition:
A base is that substance which dissociates in water to give hydroxyl ions (OH⁻).
b) Example:
H₂O
NaOH(aq) ⇌ Na⁺(aq) + OH⁻(aq)
3. Role of Water in Arrhenius Concept:
i). Water has an essential role to play in Arrhenius concept of acids and bases.
ii). Whenever an acid or a base dissociate in water, its molecules participate in reaction by surrounding the resultant proton (H⁺) and hydroxl ion (OH⁻).
iii). Since proton is very small in size and its charge density is very high, it forms a strong bond with the lone pair of water molecules to give hydroxonium ion, H₃O⁺.
Arrhenius Concept vs Brønsted-Lowry Concept
Arrhenius Concept:
i). Acid:
An acid is that substance which dissociates in water to give proton (H⁺) or hydroxonium ion (H₃O⁺).
Example:
HCl(aq) ⇌ H₃O⁺(aq) + Cl⁻(aq)
H₂O
ii). Base:
A base is that substance which dissociates in water to give hydroxyl ions (OH⁻).
Example:
NaOH(aq) ⇌ Na⁺(aq) + OH⁻(aq)
H₂O
Brønsted-Lowry Concept:
i). Acid:
An acid is a substance that donates a proton.
Example:
HCl + H₂O ⇌ H₃O⁺(aq) + Cl⁻
(Acid) (Base)
ii). Base:
A base is a substance that accepts a proton.
Example:
HCl + H₂O ⇌ H₃O⁺(aq) + Cl⁻(aq)
(Acid) (Base)
Arrhenius Concept vs Brønsted-Lowry Concept
Arrhenius Concept:
i). Acid:
An acid is that substance which dissociates in water to give proton (H⁺) or hydroxonium ion (H₃O⁺).
Example:
HCl(aq) ⇌ H₃O⁺(aq) + Cl⁻(aq)
H₂O
ii). Base:
A base is that substance which dissociates in water to give hydroxyl ions (OH⁻).
Example:
NaOH(aq) ⇌ Na⁺(aq) + OH⁻(aq)
H₂O
Brønsted-Lowry Concept:
i). Acid:
An acid is a substance that donates a proton.
Example:
HCl + H₂O ⇌ H₃O⁺(aq) + Cl⁻
(Acid) (Base)
ii). Base:
A base is a substance that accepts a proton.
Example:
HCl + H₂O ⇌ H₃O⁺(aq) + Cl⁻(aq)
(Acid) (Base)
Reaction of Sulphuric Acid with Different Compounds
1). Reaction with Ammonium Chloride:
a) Reaction:
H₂SO₄ + NH₄Cl ---> NH₄HSO₄ + HCl
b) Explanation:
Sulphuric acid reacts with ammonium chloride to form ammonium bisulphate (NH4HSO4) and release hydrogen chloride (HCl) gas.
2). Reaction with Ammonium Nitrate:
a) Reaction:
H₂SO₄ + NH₄NO₃ -- -> NH₄HSO₄ + HNO₃
b) Explanation:
Sulphuric acid reacts with ammonium nitrate to form ammonium bisulphate (NH₄HSO₄) and nitric acid (HNO₃).
3).Reaction with Magnesium Oxide:
a) Reaction:
H₂SO₄+ MgO --> MgSO₄+ H₂O
b) Explanation:
Sulphuric acid reacts with magnesium oxide to form magnesium sulphate (MgSO₄) and water (H₂O).
4). Reaction with Magnesium Carbonate:
a) Reaction:
H₂SO₄+ MgCO₃---> MgSO₄ + CO₂ +H₂O
b) Explanation:
Sulphuric acid reacts with magnesium carbonate to form magnesium sulphate (MgSO₄), carbon dioxide (CO₂) and water (H₂O).
Reaction of Base with Non-Metallic Oxide
When a base reacts with a non-metallic oxide, an acid is formed. This reaction can be represented as:
Base + Non-metallic oxide → Acid + Water
Reaction Example:
2NaOH(base) + CO₂(non-metallic oxide) → Na₂CO₃(acid) + H₂O
Nature of Non-Metallic Oxide:
From this reaction we can infer that:
- Non-metallic oxides are acidic in nature.
- They react with bases to form acids and water, which is a characteristic property of acids.
Dry HCl gas and HCl solution in water
1. Dry HCl Gas:
Reaction:
HCl + H₂O ⇌ H₃O+(aq) + Cl⁻
(acid) (Base)
Reason:
In this reaction, HCl gas acts as an acid because it donates its proton to water which acts as a base.
2. HCl Solution in Water:
Reaction:
Mg(s) + 2HCl(aq) → MgCl₂(aq) + H₂(g)
Reason:
HCl reacts with reactive metals like Mg. It forms salts and evolves hydrogen gas.
Reaction:
CaCO₃(s) + 2HCl(aq) → CaCl₂(aq) + H₂O(l) + CO₂(g)
Reason:
HCl decomposes metal carbonates and hydrogen carbonates, evolving carbon dioxide gas.
Acid vs Conjugate Base
1. Acid:
a. Definition:
An acid is a substance (molecule or ion) that can donate a proton (H⁺) to another substance.
b. Example:
HCl(aq) + NH₃(aq) ⇌ NH₄ +(aq) +Cl⁻(aq)
2. Conjugate Base:
a. Definition:
A conjugate base is a species formed when an acid donates a proton.
b. Example:
HCl(aq) + H₂O(aq) ⇌ H₃O⁺(aq) +Cl⁻(aq)
3. Explanation:
i) It is a reversible reaction.
ii) In the forward reaction HCl is an acid as it donates a proton, whereas H₂O is a base as it accepts a proton.
iii) In the reverse reaction Cl⁻ ion is a base as it accepts a proton from acid H₃O⁺ ion.
iv) Cl⁻ ion is called the conjugate base of acid HCl.
Significance of Acids within Human body
i). Acids are essential for various biochemical processes in the human body. For example, hydrochloric acid (HCl), in the stomach acids in digestion by breaking down food and killing harmful bacteria.
ii). Additionally, acids like amino acids are the building blocks of proteins and carbonic acid helps in regulating blood pH and maintaining the body's acid-base balance.
Observation of Carbon Dioxide While Passing Through Lime Water
1. For a Short Duration:
Lime water Ca(OH)₂ turns milky due to the formation of calcium carbonate CaCO₃.
a. Reaction:
CO₂ + Ca(OH)₂ → CaCO₃ + H₂O
Lime water
2. For a Long Duration:
The milkiness disappears as calcium carbonate dissolves in excess CO₂ to form calcium bicarbonate Ca(HCO₃)₂.
a. Reaction:
CaCO₃ + CO₂ + H₂O →Ca(HCO₃)₂
Calcium Carbon Water
Carbonate Dioxide